Start with a few representative VMs, not just the easiest Linux box. Windows boot storage and networking deserve a proper test.
Make sure the VirtIO storage driver is installed before switching the boot disk to a VirtIO controller. If a converted guest won't boot, a SATA controller can be a useful way to get it running while you sort out the driver, then change the boot disk last. Also check the boot order and keep console access available.
The new virtual NIC may appear as a different adapter, so static IP settings can need attention and the old adapter can linger as a hidden device. Install the guest agent and plan when to remove VMware Tools. Test the application after the guest boots, not just whether you can log in.
604miles_before_refuel:
Check the virtual switch and VLAN configuration too. A healthy guest NIC won't help if its new network isn't mapped correctly.